Journal ArticleUnknown
All-thiolate-stabilized Ag42 nanocluster with a tetrahedral kernel and its transformation to an Ag61 nanocluster with a bi-tetrahedral kernel
Authors
Author Affiliations
Anhui University, Hefei University, State Council of the People's Republic of China, Ministry of Education
Published InChemical Communications
Year2020
Citations22
Abstract
Two new silver nanoclusters, formulated as <bold>Ag42</bold>(SBu<sup>t</sup>)<sub>24</sub> and <bold>Ag61</bold>(SC<sub>6</sub>H<sub>11</sub>)<sub>40</sub>Cl were prepared by a NaSbF<sub>6</sub>-mediated two-phase ligand exchange method. A size conversion from <bold>Ag42</bold> to <bold>Ag61</bold> were achieved <italic>via</italic> cyclohexanethiol etching.
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