Photoreduction Dependent p‐ and n‐Type Semiconducting Field‐Effect Transistor Properties in Undoped Reduced Graphene Oxide

Abstract Both p‐ and n‐type field effect transistors (FET) properties have been observed in undoped reduced graphene oxide (rGO). Short and long time exposure of GO during photo reduction results in the formation of respective p‐ and n‐type rGO semiconductor. Achieving duel behavior of this type in an undoped material is exceedingly unusual. Herein we report the presence of such behavior in the reduced from of graphene oxide (rGO) for the first time.