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16+ results
Field: Chemical physics

Chemically activating MoS2 via spontaneous atomic palladium interfacial doping towards efficient hydrogen evolution

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Zhaoyan Luo, Yixin Ouyang, Hao Zhang, Meiling Xiao et al.

Journal: Nature Communications 2018
Year:
Citations: 631

Abstract Lacking strategies to simultaneously address the intrinsic activity, site density, electrical transport, and stability problems of chalcogels is restricting their application in catalytic hydrogen production. Herein, we resolve these challenges concurrently through chemically activating the...

Physical SciencesEnergyRenewable Energy, Sustainability and the EnvironmentOpen Access
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Uniform nucleation and epitaxy of bilayer molybdenum disulfide on sapphire

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Lei Liu, Taotao Li, Liang Ma, Weisheng Li et al.

Journal: NatureYear: 2022Citations: 461

Two-dimensional transition-metal dichalcogenides (TMDs) are of interest for beyond-silicon electronics 1,2 . It has been suggested that bilayer TMDs, which combine good electrostatic control, smaller bandgap and higher mobility than monolayers, could potentially provide improvements in the energy-de...

Physical SciencesMaterials ScienceMaterials Chemistry
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Room-temperature photosynthesis of propane from CO2 with Cu single atoms on vacancy-rich TiO2

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Yan Shen, Chunjin Ren, Lirong Zheng, Xiaoyong Xu et al.

Journal: Nature CommunicationsYear: 2023Citations: 334

Abstract Photochemical conversion of CO 2 into high-value C 2+ products is difficult to achieve due to the energetic and mechanistic challenges in forming multiple C-C bonds. Herein, an efficient photocatalyst for the conversion of CO 2 into C 3 H 8 is prepared by implanting Cu single atoms on Ti 0....

Physical SciencesEnergyRenewable Energy, Sustainability and the EnvironmentOpen Access
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Vacancy-defect modulated pathway of photoreduction of CO2 on single atomically thin AgInP2S6 sheets into olefiant gas

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Wa Gao, Li Shi, Huichao He, Xiaoning Li et al.

Journal: Nature CommunicationsYear: 2021Citations: 305

Abstract Artificial photosynthesis, light-driving CO 2 conversion into hydrocarbon fuels, is a promising strategy to synchronously overcome global warming and energy-supply issues. The quaternary AgInP 2 S 6 atomic layer with the thickness of ~ 0.70 nm were successfully synthesized through facile ul...

Physical SciencesEnergyRenewable Energy, Sustainability and the EnvironmentOpen Access
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Tautomeric mixture coordination enables efficient lead-free perovskite LEDs

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Dongyuan Han, Jie Wang, Lorenzo Agosta, Ziang Zang et al.

Journal: NatureYear: 2023Citations: 263

Lead-free perovskite light-emitting diodes (LEDs) prepared using tautomeric mixture coordination provide improved ordering in the crystal structure, reduced recombination and enhanced exciton binding energy compared with lead-containing perovskite-based LEDs. Lead halide perovskite light-emitting di...

Physical SciencesEngineeringElectrical and Electronic EngineeringOpen Access
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FeCl<sub>3</sub>‐Based Few‐Layer Graphene Intercalation Compounds: Single Linear Dispersion Electronic Band Structure and Strong Charge Transfer Doping

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Da Zhan, Li Sun, Zhenhua Ni, Lei Liu et al.

Journal: Advanced Functional MaterialsYear: 2010Citations: 187

Abstract Graphene has attracted much attention since its first discovery in 2004. Various approaches have been proposed to control its physical and electronic properties. Here, it is reported that graphene‐based intercalation is an efficient method to modify the electronic properties of few‐layer gr...

Physical SciencesMaterials ScienceMaterials ChemistryOpen Access
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Strain Engineering and Raman Spectroscopy of Monolayer Transition Metal Dichalcogenides

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Abdollah Motmaen Dadgar, Declan Scullion, Kyungnam Kang, Daniel V. Esposito et al.

Journal: Chemistry of MaterialsYear: 2018Citations: 175

We describe a facile technique based on polymer encapsulation to apply several percent controllable strains to monolayer and few-layer Transition Metal Dichalcogenides (TMDs). We use this technique to study the lattice response to strain via polarized Raman spectroscopy in monolayer WSe2 and WS2. Th...

Physical SciencesMaterials ScienceMaterials ChemistryOpen Access
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Composition and phase engineering of metal chalcogenides and phosphorous chalcogenides

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Jiadong Zhou, Chao Zhu, Yao Zhou, Jichen Dong et al.

Journal: Nature MaterialsYear: 2022Citations: 170

Two-dimensional (2D) materials with multiphase, multielement crystals such as transition metal chalcogenides (TMCs) (based on V, Cr, Mn, Fe, Cd, Pt and Pd) and transition metal phosphorous chalcogenides (TMPCs) offer a unique platform to explore novel physical phenomena. However, the synthesis of a ...

Physical SciencesMaterials ScienceMaterials Chemistry
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Direct observation of geometric and sliding ferroelectricity in an amphidynamic crystal

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Le‐Ping Miao, Ning Ding, Na Wang, Chao Shi et al.

Journal: Nature MaterialsYear: 2022Citations: 160

Sliding ferroelectricity is a recently observed polarity existing in two-dimensional materials. However, due to the weak polarization and poor electrical insulation in these materials, existing experimental evidences are indirect and mostly based on nanoscale transport properties or piezoresponse fo...

Physical SciencesMaterials ScienceMaterials ChemistryOpen Access
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Electron‐Phonon Coupling Suppression by Enhanced Lattice Rigidity in 2D Perovskite Single Crystals for High‐Performance X‐Ray Detection

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Bobo Zhang, Tao Zheng, Jiaxue You, Chuang Ma et al.

Journal: Advanced MaterialsYear: 2022Citations: 148

Abstract 2D Dion−Jacobson (DJ) perovskite single crystals (PSCs) usually demonstrate better X‐ray detection performance than Ruddlesden‐Popper (RP) PSCs. However, the mechanism of the improved performance is still elusive. Here, by the aid of strong interactions between dimethylbiguanide (DGA) and P...

Physical SciencesEngineeringElectrical and Electronic Engineering
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Controlled Vapor Growth and Nonlinear Optical Applications of Large‐Area 3R Phase WS<sub>2</sub> and WSe<sub>2</sub> Atomic Layers

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Zhouxiaosong Zeng, Xingxia Sun, Danliang Zhang, Weihao Zheng et al.

Journal: Advanced Functional MaterialsYear: 2019Citations: 146

Abstract 2D layered 3‐rhombohedral (3R) phase transition metal dichalcogenides (TMDs) have received significantly increased research interest in nonlinear optical applications due to their unique crystal structures and broken inversion symmetry. However, controlled growth of 2D 3R phase TMDs still r...

Physical SciencesMaterials ScienceMaterials Chemistry
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All-Optical Chirality-Sensitive Sorting<i>via</i>Reversible Lateral Forces in Interference Fields

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Tianhang Zhang, M. R. C. Mahdy, Yongmin Liu, Jinghua Teng et al.

Journal: ACS NanoYear: 2017Citations: 146

Separating substances by their chirality faces great challenges as well as opportunities in chemistry and biology. In this study, we propose an all-optical solution for passive sorting of chiral objects using chirality-dependent lateral optical forces induced by judiciously interfered fields. First,...

Physical SciencesPhysics and AstronomyAtomic and Molecular Physics, and Optics
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DFT and QTAIM investigations of the adsorption of chlormethine anticancer drug on the exterior surface of pristine and transition metal functionalized boron nitride fullerene

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Md. Rakib Hossain, Md. Mehade Hasan, Maliha Nishat, Noor-E-Ashrafi et al.

Journal: Journal of Molecular LiquidsYear: 2020Citations: 145

The application of nanomaterials as drug delivery vehicles for a vast number of anticancer drugs to reduce their severe adverse effects by transporting them into the targeted tumour cell region is currently a widely investigated novel biomedical application of various nanomaterials. In this research...

Physical SciencesMaterials ScienceMaterials Chemistry
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Femtosecond laser controlled wettability of solid surfaces

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Jiale Yong, Feng Chen, Qing Yang, Xun Hou

Journal: Soft MatterYear: 2015Citations: 141

Femtosecond laser microfabrication is emerging as a hot tool for controlling the wettability of solid surfaces. This paper introduces four typical aspects of femtosecond laser induced special wettability: superhydrophobicity, underwater superoleophobicity, anisotropic wettability, and smart wettabil...

Physical SciencesMaterials ScienceSurfaces, Coatings and FilmsOpen Access
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Size‐Dependent Optical Absorption of Layered MoS<sub>2</sub> and DNA Oligonucleotides Induced Dispersion Behavior for Label‐Free Detection of Single‐Nucleotide Polymorphism

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Bang Lin Li, Hao Zou, Lu Lu, Yu Yang et al.

Journal: Advanced Functional MaterialsYear: 2015Citations: 137

Size‐dependent optical absorption of semiconductive (2H) layered molybdenum disulfide (MoS 2 ), exhibiting great discrimination abilities to single‐ and double‐stranded DNA (ssDNA) and (dsDNA), is studied. In the presence of high concentration of salt, layered MoS 2 trends to aggregate rapidly, lead...

Physical SciencesMaterials ScienceMaterials Chemistry
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