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Fine-tuning the diradical character of molecular systems <i>via</i> the heteroatom effect

Author Affiliations
University of Electronic Science and Technology of China, Chengdu University, Hunan University, Changsha University, ...
Published InChemical Communications
Year2019
Citations43

Abstract

Heteroatoms were introduced as a novel modification strategy for fine-tuning the diradical character of molecular systems. Both the diradical character and the singlet-triplet energy gaps of diketopyrrolopyrrole based phenoxyl diradicaloids decreased as the size of the substituted heteroatoms (from O, S to Se atom) increased.
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