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Syntheses, characterization and anti‐microbial activities of palladium(II) and palladium(IV) complexes of 3,10‐C‐<b><i>meso</i></b>‐Me<sub>8</sub>[14]diene (L<sup>1</sup>) and its reduced isomeric <b><i>anes</i></b> (L<sub>A</sub>, L<sub>B</sub> and L<sub>C</sub>). Crystal and molecular structure of [PdL<sup>1</sup>][Pd(SCN)<sub>4</sub>]
Authors
Author Affiliations
University of Chittagong, Kyungpook National University, The University of Texas at San Antonio
Published InApplied Organometallic Chemistry
Year2008
Citations20
Abstract
Abstract The reactions of 3,10‐C‐ meso ‐3,5,7,7,10,12,14,14‐octamethyl‐1,4,8,11‐tetraazacyclotetradecadiene, L 1 , and two isomers (L B and L C , differing in the orientation of methyl groups on the chiral carbon atoms) of its reduced form with PdCl 2 and K 2 [Pd(SCN) 4 ], produce square‐planar tetrachloro‐ and tetrathiocyano‐palladium(II) complexes of general formulae [PdL′][PdCl 4 ] and [PdL′][Pd(SCN) 4 ] (L′ = L 1 , L B and L C ), respectively. By contrast, the third ane isomer, L A , upon reaction with the same reagents, PdCl 2 and K 2 [Pd(SCN) 4 ], formed octahedral tetrachloro‐ and tetrathiocyanato‐palladium(IV) complexes [PdL A Cl 2 ]Cl 2 and [PdL A (SCN) 2 ](SCN) 2 , respectively. The [PdL′][PdCl 4 ]…
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